Shamjad Poonoor

SHAMJAD POONOOR
chemist
Malabar Mineral Water Pullurampara
shamjadkipoonoor@gmail.com

Thursday, October 7, 2010

WATER FOR FUTURE

1.INTRODUCTION

Water is probably the most important natural sources in the world , life cannot exist and industry cannot operate. Unlike many other raw materials, there is no substitute for water in many of its uses. Water is vital for the existence of human and other life forms. Barring deep ground water, it is ceaselessly cycled by nature through atmosphere, and biosphere, water resources are hardness for drinking, irrigation, municipal and industrial uses, hydropower generation.

The word pollution derived from the latin word ‘pollutionem’ meaning defilement. Today water resources have been the most exploited natural system since man strode in earth. Pollution of water bodies is increasing steadily due to rapid growth, industrial proliferation, urbanizations increasing living standards and wide spheres of human activities. Time is, perhaps not too for when pure and clean water, particularly in densely populated industrialized water scarce areas may be inadequate for maintaining the normal living standards.

Ground water, rivers, seas, lakes, ponds and streams are founding it more and more difficult to escape from pollution. Several natural impurities that come from atmosphere, catchments areas and the soil are directly added to water so the water contains several dissolved gases (N2, CO2, H2, Cl2, NH3, SO2, NOx and H2S etc) dissolved mineral salts (Co, Fe, Mn, K, Na, Ca, Mg) suspended matters (sand, clay, and slit) and even microbes.

Even the most unpolluted geographically clean areas, the rainwater consisting of dissolved oxygen, nitrogen, co2, dust and particulates picked up from atmosphere added to the water. Now pollution of water bodies has becomes universal phenomenon in the present day world.
1.DEFINITION OF WATER POLLUTION

Water pollution may be defined in a number of ways.
Alternation in physical, chemical and biological characteristics of water, which may cause harmful, effect on human and aquatic bio data. It is also defined as addition of excess of undesirable substances to water that make it harmful to man, animal and aquatic life or other wise causes significant departures from the normal activities of various living communities in or around water.
Thus water pollution disturbs the normal use of water for irrigation, agriculture, industries, public water supply and aquatic life. It is now considered not only in term of public resources but also it represents the taste of state of deviation from pure conditions where by the normal function and properties are affected. Any shifts in the naturally dynamic equilibrium existing among environmental segments i.e. hydrosphere, atmosphere, lithosphere or sediments gives rise to the state of water pollution. Water pollution is mainly caused by natural process in which the decomposed vegetable, animal and weathered products are brought into main water resources. All these processes are interdependent on each other and lead to the deterioration of natural environment.
Anthropogenic processes such as industrial agricultural, urban, domestic, radioactive mining sources use of pesticides and fertilizers by man etc. These pollutants are constantly poured in to water and deteriorating it to such an extent that it becomes unfit for living communities.


2.TYPE OF WATER POLLUTION


Water pollution can be classified mainly in to four categories.

a)PHYSICAL POLLUTION OF WATER

The physical pollution of water brings about change in water with regards to its colour, odour, taste, turbidity and thermal properties etc.

  1. COLOUR
Colour change is not harmful unless it is associated with a toxic chemical, but it may affect the quality of sunlight that penetrates to a given depth, inhibiting plant and animal metabolism. Most of the trade wastes discharged into water system have pronounced colors due to organic dyes and inorganic complexes. Water become intensely coloured due to interaction between naturally occurring components in water and trade effluent, which make it unsuitable for various purposes.

  1. TURBIDITY
Turbidity in water mainly arises from colloidal water, fine suspended particles and solid erosion. Generally greater the turbidity stronger is the sewage and the industrial effluent concentrations are effects. Hence the degree of turbidity does not mean that water is unpolluted, because clear water that also be heavily contaminated with acids, alkalis etc; which does not cause turbidity. Turbid water becomes unsuitable for industrial purpose and also for domestic use because Fe, Mn, Ni, Co, Pb, Sb, Bi etc, present in it may cause stains on clothes, skins and baths etc.
  1. TASTE
Unpleasant earthy or musty taste and odour are produced by industrial effluent containing Fe, Mn, Free chlorine, phenol and aquatic actinomycetes Manganese, oil, hydrocarbons, Chlorophenols, petroleum products, synthetic detergents, pesticides etc, produce characteristic taste in water. The decomposed organic matter algae, fungi, bacteria and pathogens impart peculiar taste.
  1. ODOUR
Odour pollution of water is caused both by chemical agent and biological agent such as algae, fungi, microorganisms etc. lower the pH higher will be the amount of H2S produced and greatest will be the odour nuisance. Certain organic and inorganic compounds of nitrogen sulphur and phosphorus an purified organic matter present in sewage cause muddy odour to water
                                                                       
     5. FOAM
                    Foam is produced by soaps; synthetic detergent and untreated organic effluents from paper and pulp industries clean water can readily form foam. It decreases as the pollution increases.

     6.THERMAL POLLUTION
It mainly arises by the discharge of unutilized heat produced in various thermal power plants. The hated water reduces the amount of dissolved oxygen content due to which organic matter degrades faster

1.3.2 CHEMICAL POLLUTION OF WATER
The chemical pollutions of water cause changes in acidity, alkalinity, pH, dissolved oxygen and other gases in water. It may be caused either by organic pollutant can be biodegradable or non biodegradable.

Biodegradable organic pollutant includes (i) Proteins from domestic sewage waste, from creameries and slaughter houses (ii) Fats from sewage, soap production, food processing and wood processing (iii) carbohydrates, sugar, starch etc from sewage, textile mills and paper mills (iv) Polymer, resin, coal, oil and various other organic substances found in domestic and industrial wastes and those synthetic compounds which are non toxic to some micro organisms

Non-biodegradable organic pollutants are those that persist in a aquatic system for a long time. For example pesticides, nematocides etc. The use of these organic compound in chemical ultimately find their way into near by water course. Several gases, toxic metal metals and compounds have been included in inorganic pollutant because they also degrade the water quality seriously.

1.3.3 BIOLOGICAL POLLUTION OF WATER
The excretory product of warm-blooded animals including man, wild and domestic animals causes biological pollution in water. Bacteria, virus, algae etc also bring about biological pollution.

1.3.4 PHYSIOLOGICAL POLLUTION OF WATER
Physiological pollution of water is caused by several chemical agent such as chlorine, sulpher dioxide, ketone, phenols, amines, chlorination of water usually convert phenol to ortho or para chlorophenol which tasted like medicine and produce offensive odour.

GROUND WATER
POLLUTION

Today the accelerated pace of development, rapid industrialsation and population density have increased demand of water resources, ground water a gift of nature, is about 210 billion m3 including recharge though infiltration, sewage and evaporation out of this nearly one third is extracted fro irrigation industrial and domestic use while most of the water is regenerated in to river.
Ground water act as reservoir by the virtue of long pore space in earth materials as a contain which can transport water long and as a mechanical filter. Which improved water quality by removing suspended social and bacterial contamination. It is a source of water for well and springs, that is the recommended for rural domestic use.
Ground water contamination is generally irreversible once it is contaminated; it is difficult to restore the original water quality.
The extent of ground water pollution depend on the following factors (i) Rain fall pattern (ii) Depth of water table (iii) Distance from the sources of contamination and soil properties such as texture structure and filtration rate.

      1. SOURCE OF CONTAMINATION OF GROUND WATER
Under ground source of drinking water, especially in outskirts of large cities and village are highly polluted. Ground water is threatened with pollution from the following source such as domestic waste, industrial waste, agricultural waste, runoff from urban area and soluble effluents.

1.4.2 HARMFUL EFFECTS OF GROUND WATER POLLUTION
Ground water pollution causes irreparable damage to soil, plant and animals including man. Polluted water is the major causes fro spread of epidemics and erotic disease in man. It causes typhoid, hepatitis, dysentery, and tuberculosis. Water contaminated by fibers i.e. asbestos causes fatal diseases like lung cancer ground water in excessive rainfall area contamin iron in topic amount as 20 ppm in deep tube wells, iron exists as ferrous ion which on taking out rapidly changes to light yellow orange colour due to oxidation and precipitation as ferric hydroxides.
The use of polluted ground water for irrigating agriculture fields several damages crops and decreases grain production Polluted water acutely affected soil fertility by killing bacteria and soil micro organism
    1. WATER QUALITY
Experience has shown that many divers factors will have to be taken into account before making comment on water quality. For this reason the concentration of inorganic and organic substance dissolved in a body of water their spatial and temporal variation need to be monitored. It has been classified on the basis of their total dissolved solid contents as given in table 1.1.




TABLE 1.1 WATER QUALITY Vs TOTAL DISSOLVED SOLID











Water Quality
Total Dissolved Solid (mg/l)
Fresh
Less than 1000
Slight saline
1000 to 3000
Moderately saline
3000 to 10000
Very saline
10000 to 35000
Bring
Grater than 35000


The underlying chemical relationship between pH, alkalinity, hardness, the ratio of sodium to that of calcium and magnesium etc. determines the buffering capacity, deposit formation and corrosive nature of water.


TABLE 1.2 CHEMICAL CONSTITUENTS OF SIGNIFICANCE IN NATURE WATER
Chemical Constituents mg/l
Bicarbonate 150-200
Carbonates ---------
Calcium ---------
Magnesium 25-50
Sodium 60 (irrigation)
Iron Less than 1
Manganese Less than 0.05
Chloride 200
Fluoride 0.7 – 1.2

1.5.1 DRINIKING WATER SUPPLIES
The quality of water for domestic use judged from its total dissolved solid content. The WHO has stipulated the drinking water should have TDS content less than 500mg/l in case no alternative supply is available Drinking water should also be free from colour and turbidity. It should have no unpleasant colour (dissolved gas) or taste.

A case in point is the smell of chlorine that is once in a way detected in domestic water, supply, as a result of excessive chlorination with on increase in hardness of water its suitability decreases with respect to cooking, cleaning. One the well documented problem concerning drinking water is the presence of fluoride. There is also a certain amount of avoidable confusion since the beneficial effect of a little fluoride in dental case is also known.




TABLE 1.3 WHO GUIDELINES (1984) FOR ESTHETIC
QUALITY OF DRINKING WATER









Constituent
Unit
Guideline Value
Chloride
mg/l
200
Copper
mg/l
1.0
Hardness
mg/l
500 (as CaCo3)
Iron
mg/l
0.3
Manganese
mg/l
0.1
pH
-
6.5 to 8.5
Sodium
mg/l
200
Sulphate
mg/l
400





1.5.2 CHEMICAL PARAMETERS GOVERNING WATER QUALITY
It is essential to appreciate the significance of limit set on chemical parameter defining water quality. The hydrogen ion concentration is represented by the value pH. The electrical conductivity of water is related to its total dissolved solid content since it is easy to measure the parameter. It is a very useful indicator and is expressed as micro siemens/cm at 25.c.

TABLE 1.4 SPECIFICATION CONDUCTIVITY Vs WATER QUALITY









Specific conductivity (s/cm)
Water quality
Less than 250
Excellent
250 – 750
Good
750 – 2000
Permissible
2000 – 3000
Need treatment
Greater than 3000
Unsuitable for most purposes

A commonly indicated water quality parameter is hardness, in presence of Ca and Mg in combination with anions such as carbonates and sulpahte. The presence of these two divalent cation is essential for ensuring soil permeability as well as for the growth of groups. Thus one measures about is known as Ca hardness Mg hardness and sum of these two viz the total hardness.

TABLE 1.5 HARDNESS Vs WATER QUALITIES.








Hardness in mg/l CaCo3
Description of water
0 – 50
Soft water
50 – 100
Moderately soft
100 – 150
Neither bard or soft
150 – 200
Moderately bard
200 – 300
Hard water
Bore water 300
Very hard


save water

Sunday, September 12, 2010

TYPE OF TEA AND ITS HEALTH BENEFITS


TYPE OF TEA


Black tea
Green tea
Oolong tea
Silvertips tea
Handmade tea

Black Tea

Black tea manufacturing is normally carried out in two ways

i)CTC
ii)Orthodox

CTC refers to the Crush,Tear and Curl process.Here the plucked leaves undergo withering process where there is a certain amount of moisture loss. Then the withered leaves are passed through the two rollers rotating in opposite direction. Herethe leaves are crushed,torn and curled.

In orthodox type manufature the withered leaves are rolled on specially designed orthodox roller which twist and crush the leaves thereby rupturing the cells

After the above mentioned two methods of rolling process the dhools undergo the process of fermentation and finally the drying process.

Green Tea

Green Tea are mainly manufatured by two method namelly

i)Steaming
ii)Panning

Green Tea differs from Black tea in so much that oxidation is not allowed to occur.After withering process the leaf enzyme is destroyed by heating with either steam or dry heating (panning).

Steaming is almost instant in its enzyme kill,these teas typically have a very green liquor. In the steaming process,the inactivation ofenzyme is achived by steaming the flush to the temperature of 100degree c.

The panning or roasting method allow a small amount of oxidation that typecally occurs the liqour yellow.In this method fresh shoots are expossed to a blast of hot air at 100 to 106degree C.Fresh leaves are fed into a barrel for 3 to 4 min.thus the inactivation of polyphenol oxidase enzyme is brought about by dry heat in the panning process.

After heat treatment the green tea manufacture process is similar to that of orthodox method.

Oolong Tea

Oolong tea is semi oxidised tea. The plucked leaves are initially withered in the sun upto an hour. Then they are withered again at room temperature.

AT this stage, the leaves are stirred and tossed many times by hand. This cause slight bruising of leaves due to which natural fermentation starts.At the end of withering stage,the leaves are subjected to panfiring which arrest fermentation.

Thus the leaves are partially fermented yielding a flavour characteristic to Oolong teas.The leaves are then rolled,fired again,cold rolledfired for a final time.

Silvertips Tea

Silvertips are generally produced by plucking only buds and drying in natural sunlight.This allow the tips retain their covering of velvety silvery colour.

In the sun drying process the buds could be spread on nylon nets.Drying should be done at an optimum temperature.






Handmade Tea

Handmade tea,as the name suggests,is the tea made from rolling the leaves gently by hands.Handmade tea is processed from leaves containg only single,two leaf and buds.The plucked leaves aare subjected to a hard wither.

The withered leaves are then gently rolled by hand.After 30 second the leaves are seperated and again hand rolled with increased pressure.Tottaly the shoots are rolled for about one minute. After rolling the leaves are fermentated in the floor and finally dried.

HEALTH BENEFITS OF TEA

what in tea?

Tea contains a small amount of necessary vitamins as well as mineral element such as Manganese,Zinc,Potassium and Megnesium.

Tea is a very good source of Antioxidents.The antioxident present in thetea prevent the oxidation reaction initiated by the free radicals by interacting with them. The oxidation reaction can cause damage to the cell components.Thus the antioxidents property of the teahelps to strengthen the immune system of the body.

Heart Benefits :

Tea decreases the risk of developing heart disease.Higher black tea consuption corresponted with fewer fatel heart attacks.

Cancer Prevention

Tea protect against the development of pancreatic and prostate cancer.Green tea couldhelp stem esphagenal cancer.Tea consumption may lower stomac cancer risk

Hypertension Reducing Benefits :

Green and Oolong tea reduce the risk of hypertension

Oral hygiene:


Tea protect tooth decay and inhibit plaque formation Tea provide a small natural source of fluride







special thanks to
Jasin Rahman
Research Scholar,
UPASI TRF, Valparai,
-from 'Anamalai Tiger reserve

Sunday, September 5, 2010

Why do we cry when we cutting onion?


Inside the onion cells there are some chemical compounds which contain sulfur. When you cut an onion its cells are broken and those chemical compounds then undergo a reaction that transforms them into a more volatile sulfured products, which are released into the air.

These sulfured compounds react with the moisture in your eyes forming sulfuric acid, which produces a burning sensation. The nerve endings in your eyes are very sensitive and so they pick up on this irritation. The brain reacts by telling your tear ducts to produce more water, to dilute the irritating acid. So you cry to keep your eyes protected from the acid.


There are some tricks to make onion-dicing less problematic:
- Chop the onion under cold water. The volatile sulfured compounds will be released but then they react with the water, instead of reaching your eyes.
- You can freeze the onion for 10 minutes before cutting it. The cold temperature of the onion will slow down the chemical reaction which forms the volatile sulfured compunds

Source(s):